We already know a few card which will reprinted in this Structure deck, but the main monster of the deck is now revealed, and it is Shadow of the Six Samurai - Shien :
Effect : 2 Level 4 "Six Samurai" monsters
Once per turn, during either player's turn: You can detach 1 Xyz Material from this card to target 1 face-up "Six Samurai" monster you control with less than 2000 ATK; its original ATK becomes 2000 until the End Phase.
Spoiler (41/41) :
Chamberlain of the Six Samurai
Grandmaster of the Six SamuraiThe Six Samurai - Yariza
The Six Samurai - Zanji
The Six Samurai - Nisashi
The Six Samurai - Yaichi
The Six Samurai - Kamon
The Six Samurai - Irou
Great Shogun Shien
Shien's Footsoldier
Enishi, Shien's Chancellor
Spirit of the Six Samurai
Future Samurai
The Immortal Bushi
Hand of the Six Samurai
Legendary Six Samurai - Kizan
Legendary Six Samurai - Enishi
Legendary Six Samurai - Kageki (Super Rare)
Shien's Squire
Shien's Daredevil
Elder of the Six Samurai
Shien's Advisor
Dark Hole
The A. Forces
Reinforcement of the Army
The Warrior Returning Alive
Cunning of the Six Samurai
Six Samurai United
Gateway of the Six
Shien's Smoke Signal (Super Rare)
Temple of the Six
Shien's Dojo
Rivalry of Warlords
Return of the Six Samurai
Double-Edged Sword Technique
Fiendish Chain
Musakani Magatama
Shien's Scheme
Six Strike - Thunder Blast
Six Style - Dual Wield
Shadow of the Six Samurai - Shien (Ultra Rare)
By the way, Legendary Six Samurai - Shi En will not be in the Structure Deck, but will be in the Special Edition Ra Yellow Mega Pack as a promo card :
Oh, and here is a pick of the paper mat which will be in the Structure Deck :
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